Book Time Off emails you automatically. You get a confirmation when you submit, and the decision when your leave is approved or declined. Approvers get a request email with one-click Approve and Decline links.
The submit, approve and decline emails are sent automatically and are not individually switched off. There are no reminder emails.
If your company has connected Slack or Microsoft Teams, requests and decisions arrive there as direct messages too, with the same one-click Approve and Decline buttons for approvers. Google Chat can post the daily who's-off digest and let people book leave, with the approval decision sent to the approver by email. See Use Book Time Off in Slack and Use Book Time Off in Google Chat.